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Yes, superglue is safe in the tank. But… and I’m just wondering here. Is it safe if it’s ingested. Not toxic. But coins are inert when small children swallow them. Socks are safe when dogs eat them. But I’ve known both things to cause serious issues. I’d scrape off as much as possible. And you’ll like the look better knowing that it’s mostly gone. 

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If the glue is looking ugly (looks white under water), you can glue some non-toxic fiber material like burlap, or plants over top of it.
The plecos might eat that too, but you can often hide your mess ups by adding small rocks or something.

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