I've never seen them eat biofilm. I guess in the absence of fresh algae, or a quality dry food, they may, but I wouldn't rely on this. They are also picky about the age of the algae they graze, and prefer fresh young algae to established algae.
In both the tanks where I have otos, they devour Repashy Super Green--they even guard it when I put it in the tank. And, i have to mow down the algae farm on the rear glass every now and again so it replenishes with nice young growth.
They completely ignore the biofilm masses when they develop, though.