Greetings,
With the exception of my rimless tanks, all my aquariums have their backs painted. Black is my preference, but I’ve done sky blue, forest green, and even orange (for my reef tank). Between brush coating and spraying, spray painting is totally the fastest and most efficient way. It maybe takes 45 minutes total for prepping, actual spraying, and waiting in-between coats (honestly waiting around for paint to dry takes the most time; 20-30 minutes or so). When completed, as long as you’re careful moving your tank after it’s dry to touch, it should be pretty durable for a long time.
I’ve found that planning ahead of time for spray painting is the key. Doing it outside away from anything you shouldn’t get overspray on (like your neighbor’s car, or your own white picket fence), when it’s above 50 degrees F, and also in an area protected from rain, you can do it without much fuss or mess.
The prep time if done properly (tape off the sides and open top with newspaper and painters tape) will take no more than 10-15 minutes. Enjoy the experience!